Conductivity and dissociation behaviour of Lactic acid in the aqueous solutions of poly(ethylene glycol) at different temperatures
کد مقاله : 1193-PHYSCHEM20
نویسندگان:
1Abbas Mehrdad *، 2حمایت شکاری، 1Narmin Noorani
1Tabriz University
2دانشگاه تبریز
چکیده مقاله:
In this study, influence of poly(ethylene glycol) (PEG) on the electrical conductivity of L(+)-lactic acid (LaH) have been investigated. The molar conductivities of LaH in aqueous solutions of PEG were measured at T = (288.15-318.15) K. These data have been analyzed by Quint-Viallard (QV) conductivity equation and the limiting molar conductivities (Λ0), dissociation constants ( ), and Walden product (Λ oη) were calculated. The results indicate that the values of Λ 0 decrease by increasing concentration of PEG and increase by increasing temperature. Also, the Λ oη values decrease by increasing temperature which can be related to the dehydration of ions at higher temperatures.
کلیدواژه ها:
Lactic acid; Poly(ethyleneglycol); Quint-Viallard (QV)conductivity equation; Dissociation constants; Molar conductivity.
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